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SingaporeChemistryQuick questions

Organic Chemistry

Quick questions on Arenes, benzene and electrophilic substitution: Singapore A-Level H2 Chemistry

5short Q&A pairs drawn directly from our worked dot-point answer. For full context and worked exam questions, read the parent dot-point page.

What is the structure of benzene?
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Benzene, C6H6\text{C}_6\text{H}_6, is a planar, regular hexagon. Each carbon is sp2sp^2 hybridised and forms three sigma bonds (to two carbons and one hydrogen). The remaining p orbital on each carbon, perpendicular to the ring, overlaps sideways with its neighbours to form a continuous ring of delocalised pi electrons above and below the plane.
What is evidence for delocalisation?
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The delocalised model is supported by three lines of evidence against the Kekule alternating-double-bond structure:
What is q1?
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State two pieces of evidence for the delocalised structure of benzene. [2 marks]
What is q2?
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Write the equation for the formation of the electrophile in the nitration of benzene. [1 mark]
What is q3?
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State the reagents and catalyst for the chlorination of benzene, and name the product. [2 marks]

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